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level: haloalkanes

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level questions: haloalkanes

QuestionAnswer
Naming haloalkanesf- FLURO CL- CHLORO BR-BROMO I-IODO
Haloalkanes donate a nucleophiles what is a nucleophileelectro pair donor
Hydrolysis of haloalkane -- nucleophillic substituionThe nucleophile, OH – , approaches the carbon atom attached to the halogen on the opposite side of the molecule from the halogen atom. • This direction of attack by the OH –minimises repulsion between the nucleophile and the δ– halogen atom • A lone pair of electrons on the hydroxide ion is attracted and donated to the δ+ carbon atom. • A new bond is formed between the oxygen atom of the hydroxide ion and the carbon atom 2. The carbon – halogen bond breaks by heterolytic fission 3. The new organic product is an alcohol, a halide ion is also formed
Bonds strength of haloalkanesFluroalkanes are strongest
Rate of hydrolysis/Testing for haloalkanes .chlorbutane - white [recipate bromobutane -cream idobutane - yellow Rate of hydrolysis increases as the strength of the carbon halogen decreases
Organohalogen compounds in the envrionmentCFCs break down UV light to form radicals catalysing the ozone layer