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Question:

Both sigma (σ) and pi (π) bonds can be formed by overlapping p orbitals. Describe the difference.

Author: Sena Aysel



Answer:

Sigma bonds are formed from the overlap of atomic orbitals along a circular axis of symmetrical nature, i.e., head-on overlap. All single bonds are sigma bonds. Pi bonds are formed from the overlap of atomic orbitals along a non-symmetrical (parallel) axis, i.e., side-to-side overlap. Double and triple bonds are pi bonds.


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