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Question 2 Organic Chemistry

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Question:

Consider the set of compounds, NH3, HF, and H2O. Rank these compounds in order of increasing acidity and discuss your rationale

Author: Sena Aysel



Answer:

NH3 < H2O < HF When determining relative acidity, it is often useful to look at the relative basicity of the conjugate bases. The stronger the acid, the weaker (more stable, less reactive) the conjugate base. In this case, one would look at the relative basicity of F-, OH-, and NH2-. The relative strengths of these species can be gauged based on the electronegativity of the charged atom in each base. Since fluorine is the most electronegative, F- is the most stable, least reactive base in the group. This means that its conjugate acid, HF, is the strongest.


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