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CHEMISTRY: TOPIC 13 PERIODICITY

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Question:

How can we deduce which complex ion will have greater splitting of the 3d orbital if they have the same number of electrons? (5)

Author: Sammy Universe



Answer:

The complex ion with the higher nuclear charge on the metal ion = bec it causes the ligands to be pulled in closer to the metal ion = greater repulsion bw the ligand electrons and the d electrons of the metal ion = greater splitting of the d orbitals EG: [Mn(H2O)6]2+ and [Fe(H2O)6]3+ both have 5 3d electrons = greater splitting in the Fe ion bec it has 26+


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